Henri Becquerel

In Becquerel’s early career, he became the third in his family to occupy the physics chair at the Muséum National d’Histoire Naturelle in 1892. Later on in 1894, Becquerel became chief engineer in the Department of Bridges and Highways before he started with his early experiments. Becquerel’s earliest works centered on the subject of his doctoral thesis: the plane polarization of light, with the phenomenon of phosphorescence and absorption of light by crystals. Early in his career, Becquerel also studied the Earth’s magnetic fields.

Becquerel’s discovery of spontaneous radioactivity is a famous example of serendipity, of how chance favors the prepared mind. Becquerel had long been interested in phosphorescence, the emission of light of one color following a body’s exposure to light of another color. In early 1896, there was a wave of excitement following Wilhelm Conrad Röntgen’s discovery of X-rays on 5 January. During the experiment, Röntgen “found that the Crookes tubes he had been using to study cathode rays emitted a new kind of invisible ray that was capable of penetrating through black paper”. Learning of Röntgen’s discovery from earlier that year during a meeting of the French Academy of Sciences caused Becquerel to be interested, and soon “began looking for a connection between the phosphorescence he had already been investigating and the newly discovered x-rays” of Röntgen, and thought that phosphorescent materials, such as some uranium salts, might emit penetrating X-ray-like radiation when illuminated by bright sunlight.

By May 1896, after other experiments involving non-phosphorescent uranium salts, he arrived at the correct explanation, namely that the penetrating radiation came from the uranium itself, without any need for excitation by an external energy source. There followed a period of intense research into radioactivity, including the determination that the element thorium is also radioactive and the discovery of additional radioactive elements polonium and radium by Marie Skłodowska-Curie and her husband Pierre Curie. The intensive research of radioactivity led to Henri publishing seven papers on the subject in 1896. Becquerel’s other experiments allowed him to research more into radioactivity and figure out different aspects of the magnetic field when radiation is introduced into the magnetic field. “When different radioactive substances were put in the magnetic field, they deflected in different directions or not at all, showing that there were three classes of radioactivity: negative, positive, and electrically neutral.”

As often happens in science, radioactivity came close to being discovered nearly four decades earlier in 1857, when Abel Niépce de Saint-Victor, who was investigating photography under Michel Eugène Chevreul, observed that uranium salts emitted radiation that could darken photographic emulsions. By 1861, Niepce de Saint-Victor realized that uranium salts produce “a radiation that is invisible to our eyes”. Niepce de Saint-Victor knew Edmond Becquerel, Henri Becquerel’s father. In 1868, Edmond Becquerel published a book, La lumière: ses causes et ses effets (Light: Its causes and its effects). On page 50 of volume 2, Edmond noted that Niepce de Saint-Victor had observed that some objects that had been exposed to sunlight could expose photographic plates even in the dark. Niepce further noted that on the one hand, the effect was diminished if an obstruction were placed between a photographic plate and the object that had been exposed to the sun, but ” … d’un autre côté, l’augmentation d’effet quand la surface insolée est couverte de substances facilement altérables à la lumière, comme le nitrate d’urane … ” ( … on the other hand, the increase in the effect when the surface exposed to the sun is covered with substances that are easily altered by light, such as uranium nitrate … ).